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Adv. Mater. Interfaces 2025, 2400661
A Pathway Toward Sub-10 nm Surface Nanostructures Utilizing Block Copolymer Crystallization Control
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It is elucidated how crystallization can be used to create lateral surface nanostructures in a size regime toward sub-10 nm using molecular self-assembly of short chain crystallizable block copolymers (BCP) and assist in overcoming the high-χ barrier for microphase separation. In this work, an amphiphilic double-crystalline polyethylene-b-polyethylene oxide (PE-b-PEO) block co-oligomer is used. A crystallization mechanism of the short-chain BCP in combination with neutral wetting of the functionalized substrate surface that permits to form edge-on, extended chain crystal lamellae with enhanced thermodynamic stability. In situ atomic force microscopy (AFM) analysis along with surface energy considerations suggest that upon cooling from the polymer melt, the PE-b-PEO first forms a segregated horizontal lamellar morphology. AFM analysis indicates that the PEO crystallization triggers a morphological transition involving a rotation of the forming extended chain crystals in edge-on orientation. Exposing their crystal side facets to the top surface permits to minimize their interfacial energy and form vertical nanostructures. Moreover, the edge-on lamellae can be macroscopically aligned by directed self-assembly (DSA), one necessity for various nanotechnological applications. It is believed that the observed mechanism to form stable edge-on lamellae can be transferred to other crystallizable short chain BCPs, providing potential pathways for sub-10 nm nanotechnology.
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from our users
Adv. Funct. Mater. 2025, 2418186
Conformation‐Driven Nickel Redox States and Magnetism in 2D Metal–organic Frameworks
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2D metal–organic frameworks (2D MOFs) attract considerable attention because of their versatile properties and as potential candidates for single-atom catalysis, high-density information storage media or molecular electronics and spintronics devices. Their unique characteristics arise from an intricate interplay between the metal center, the surrounding ligands and the underlying substrate. Here, the intrinsic magnetic and electronic properties of a single-layer MOF on graphene is investigated with a combination of spectroscopic techniques and theoretical modeling. Taking advantage of the weak interaction between the MOF and graphene substrate, it is specifically focused on the influence of the coordination environment on these properties. Notably, two distinct coordination configurations are observed for the transition metal centers within the 2D MOF, and clarify how axial distortions in the ligand field affect the hybridization between the Ni 3d states and the π-symmetric molecular orbitals of 7,7,8,8-tetracyanoquinodimethane ligands, leading to the coexistence of two Ni redox states with different spin configurations. Furthermore, the transition from a nearly free-standing MOF is examined to metal-supported frameworks, elucidating the impact of substrate interactions on the electronic and magnetic properties. The findings advance the understanding of MOFs and offer insights into developing functional materials with tailored magnetic and electronic properties.
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from our users
Inorg. Chem. Front., 2025, Advance Article
Robust high-spin Fe2+ centers in 2D TCNQ-based metal-organic frameworks
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Two-dimensional metal–organic frameworks (2D MOFs) are atomically thin materials that combine the properties of organic molecules with the structural characteristics of crystalline inorganic solids. Their unique magnetic and electronic properties arise from the interaction between transition metal centers and organic linkers. This study focuses on the high-spin Fe2+ centers in a 7,7,8,8-tetracyanoquinodimethane (TCNQ)-based 2D MOF, where hybridization between Fe 3d states and π-symmetric orbitals of TCNQ ligands stabilizes regularly spaced magnetic centers. X-ray magnetic circular dichroism (XMCD) measurements confirm the robustness of these magnetic properties across various substrates, including graphene and gold.
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Deliverables view all
WP11 - JA1 - Real-time observation and control in microscopy and spectroscopy of nano-objects
D11.7 - Implementation of STM microscopy for investigation of solid/liquid interfaces under welldefined gas atmospheres and with electrochemical control (EC-STM)
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Investigating materials and processes in realistic environments is crucial for understanding and designing materials for applications in energy storage, catalysis, corrosion resistance, and nanotechnology. In this context, one of the key objectives of JA1 is to integrate operando capabilities into scanning tunneling microscopy (STM) experiments in multiphase environments. Specifically, sub-task 11.1.2 focuses on setting up versatile electrochemical STM (EC-STM) systems and developing user-friendly protocols for in-situ electrochemical STM, enabling operation at solid/liquid interfaces under well-defined gas atmospheres and with electrochemical control. To this end, two custom-built EC-STM systems have been set up that are based on the same platform developed by the Wandelt research group (Uni Bonn) that is characterized by a rugged design, great flexibility concerning various electro-chemical environments, and excellent performance regarding lateral spatial resolution [1]. While the system at ICN2 has been developed to offer optimized, user-friendly protocols for external users and will complement the advanced characterization tools available at ICN2 through the NFFA, the reference system at TUM has been optimized to host high-speed capabilities, enabling operando experiments on electrochemically relevant systems with sub-s time resolution. Given TUM's extensive technical and research experience in electrochemical STM, and the fact that both systems share the same design, the transfer of knowledge in nearly all technical aspects has been crucial for the successful implementation of the ICN2 system.
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WP12 - JA2 - X-ray Wavefront Metrology, Correction and Manipulation
D12.5 - User Experiment with OAM beam
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Electromagnetic waves with orbital angular momentum (OAM) are increasingly used in optical communications, quantum technologies, and optical tweezers. Recently, they have shown potential for detecting helical dichroic effects in chiral molecules and magnetic nanostructures. In this study, we used single-shot ptychography on a nanostructure with extreme ultraviolet OAM beams of varying topological charge (ℓ) at a free-electron laser. By adjusting ℓ, we improved image resolution by 30% compared to standard Gaussian beams, advancing coherent diffraction imaging and enabling sub-100 nm time-resolved microscopy over large sample areas.
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WP13 - JA3 Nano-engineering and pattern transfer methods
D13.4 - Library of processes based on advanced nano-engineering for TA
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In the current document we report on a selection of new processes developed within the NFFA (NEP) project related to advanced nanoengineering for transnational access (TA). They form a new library of process steps enabling new or improved capabilities for some specific nanopatterning. They are complementary and generally compatible with state-of-the-art microelectronics industry. Besides developing the individual core technology, we paid particular attention to novel groupings in a mix-and-match approach to study possible combinations of processes to maximize enabling capabilities for nanosystems manufacturing.
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Transnational Access Statistics
28 calls for access
970 proposals submitted
63% rate of acceptance
29% with Large Scale Facilities
12% with theory
11% with industry
~3 average users per proposal
65 countries applying
2949 lab sessions